THE CARBON NANOTUBES GROWN ON MOLYBDENUM SUBSTRATESBY CVD-METHOD USING THIN METAL FILMS OF IRON AND WATER SOLUTIONS OF FERRIFEROUS SUBSTANCES AS CATALYSTS


Cite this article as:

Tarasov Е. А., Sinitsyn N. I., Grigoriev Y. А., Bourtsev А. А. THE CARBON NANOTUBES GROWN ON MOLYBDENUM SUBSTRATESBY CVD-METHOD USING THIN METAL FILMS OF IRON AND WATER SOLUTIONS OF FERRIFEROUS SUBSTANCES AS CATALYSTS. Izvestiya VUZ. Applied Nonlinear Dynamics, 2012, vol. 20, iss. 3, pp. 108-117. DOI: https://doi.org/10.18500/0869-6632-2012-20-3-108-117


The synthesis of carbon nanotubes is carried out on the surface of molybdenum substrates by CVD-method using thin-film iron and water solutions of ferritin and iron acetate as catalysts sources. It is found that the temperature of process technology in the synthesis of carbon nanotubes on molybdenum substrates must be above 900 ◦C. At this point, only non-uniform films of carbon nanotubes on the surface of molybdenum substrates were obtained. It is shown that the formation of carbon nanotubes in the local areas of the surface of molybdenum determined by its structure but not the type of catalyst used. Obtained samples were investigated by means of scanning electron microscopy and optical microscopy.

DOI: 
10.18500/0869-6632-2012-20-3-108-117
Literature

1. Cattien V. Nguyen, Qi Ye, M. Meyyappan. Carbon nanotube tips for scanning probemicroscopy: Fabrication and high aspect ratio nanometrology // Measurement Science and Technology. 2005. Vol. 16, No 11. Р. 2138.

2. Ting Zhang, Syed Mubeen, Nosang V. Myung, Marc A. Deshusses. Recent progress in carbon nanotube-based gas sensors // Nanotechnology, 2008. Vol. 19, No 33. Р. 332001.

3. Qi Dong Zhang, Benoit Piro, Vincent Noel, Steeve Reisberg and Minh-Chau Pham. Applications of carbon nanotubes to electrochemical DNA sensors: A new strategy to make direct and selective hybridization detection from SWNTs // Advances in Natural Sciences: Nanoscience and Nanotechnology. 2010. Vol. 1, No 4. Р. 045011.

4. Lin Xiao, Yuying Zhang, Yang Wang, Kai Liu, Zheng Wang, Tianyi Li, Zhe Jiang, Junpeng Shi, Liang Liu, QunQing Li, Yonggang Zhao, Zhenghe Feng, Shoushan Fan and Kaili Jiang. A polarized infrared thermal detector made from super-aligned multiwalled carbon nanotube films // Nanotechnology. 2011. Vol. 22, No 2. Р. 025502.

5. Елецкий А.В. Холодные полевые эмиттеры на основе углеродных нанотрубок // Успехи физических наук. 2010. Т. 180, No 9. С. 897.

6. Волкова З.П., Хотин В.М. Технология электровакуумных материалов. Л.: Энергия, 1972. 216 с.

7. Дерягин Б.В., Федосеев Д.В. Рост алмаза и графита из газовой фазы. М.: Наука, 1977. 116 с.

8. Тарасов Е.А., Буянова З.И., Синицын Н.И., Торгашов Г.В., Самарский М.В. Синтез тонких пленок из углеродных нанотрубок методом пиролитического разложения углеводородов в присутствии катализатора // Всероссийская конференция с элементами научной школы для студентов, аспирантов и молодых ученых «Приборное и научно-методическое обеспечение исследований и разработок в области микро- и наноэлектроники» (22–27 ноября 2010, БашГУ, Уфа): Лекции и научные статьи / Отв. ред. С.С. Гоц. Уфа: РИЦ БашГУ, 2011. С. 220.

9. Tarasov E.A. The use of liquid catalysts for synthesis of carbon nanotubes // Материалы Международной научно-практической Интернет-конференции «Молодые ученые за инновации: создавая будущее» в рамках Международного Интернет-фестиваля молодых ученых, 27–29 апреля 2011, СГТУ, Саратов) / Под ред. Л.А. Скворцовой. Саратов: Изд-во СГТУ, 2011. С. 31.

10. Yoshikazu Nakayama, Lujun Pan and Goichi Takeda. Low-temperature growth of vertically aligned carbon nanotubes using binary catalysts // Japanese Journal of Applied Physics. 2006. Vol. 45, No 1A. P. 369.

11. Shang N.G., Tan Y.Y., Stolojan V., Papakonstantinou P. and Silva S.R.P. High-rate low-temperature growth of vertically aligned carbon nanotubes // Nanotechnology. 2010. Vol. 21, No 50. Р. 505604.

12. Диаграммы состояний двойных металлических систем. Справочник в трех томах / Под общей редакцией академика РАН Н.П. Лякишева. М.: Машиностроение, 1996. Т. 1.

13. Фурсиков П.В., Тарасов Б.П. Каталитический синтез и свойства углеродных нановолокон и нанотрубок // International Scientific Journal for Alternative Energy and Ecology. 2004. T. 18, No 10. С. 24. 

Status: 
одобрено к публикации
Short Text (PDF): 

BibTeX

@article{Тарасов -IzvVUZ_AND-20-3-108,
author = {Е. А. Tarasov and N. I. Sinitsyn and Y. А. Grigoriev and А. А. Bourtsev},
title = {THE CARBON NANOTUBES GROWN ON MOLYBDENUM SUBSTRATESBY CVD-METHOD USING THIN METAL FILMS OF IRON AND WATER SOLUTIONS OF FERRIFEROUS SUBSTANCES AS CATALYSTS},
year = {2012},
journal = {Izvestiya VUZ. Applied Nonlinear Dynamics},
volume = {20},number = {3},
url = {https://old-andjournal.sgu.ru/en/articles/the-carbon-nanotubes-grown-on-molybdenum-substratesby-cvd-method-using-thin-metal-films-of},
address = {Саратов},
language = {russian},
doi = {10.18500/0869-6632-2012-20-3-108-117},pages = {108--117},issn = {0869-6632},
keywords = {Nanotechnology,carbon nanotubes,refractory metals,field emission cathodes,scanning electron microscopy,optical microscopy.},
abstract = {The synthesis of carbon nanotubes is carried out on the surface of molybdenum substrates by CVD-method using thin-film iron and water solutions of ferritin and iron acetate as catalysts sources. It is found that the temperature of process technology in the synthesis of carbon nanotubes on molybdenum substrates must be above 900 ◦C. At this point, only non-uniform films of carbon nanotubes on the surface of molybdenum substrates were obtained. It is shown that the formation of carbon nanotubes in the local areas of the surface of molybdenum determined by its structure but not the type of catalyst used. Obtained samples were investigated by means of scanning electron microscopy and optical microscopy. }}